Based on observation data and a novel K-mean clustering method, we investigated whether intrinsic atmospheric circulation patterns are related with the occurrence of high particulate matter (PM) concentration days (diameters less than or equal to 2.5 μm (PM_2.5)), in Seoul, South Korea, during the cold season (December to March). A simple composite map shows that weak horizontal and vertical ventilation over the Korean Peninsula can cause high PM_2.5 concentration (High_PM_2.5) days. Also, atmospheric circulations are quite different between one day of High_PM_2.5 and periods longer than two days. We also found that two intrinsic atmospheric circulation patterns in Asia, which were obtained by adopting K-mean clustering to the daily 850 hPa geopotential height anomalies for 2005-2020, were associated with High_PM_2.5 days. These results indicate that High_PM_2.5 days in Seoul, South Korea, occur as a result of intrinsic atmospheric circulation patterns, therefore, they are unavoidable unless the anthropogenic emission sources over the Korean Peninsula, East Asia, or both are reduced. In addition, these two intrinsic atmospheric circulation patterns are more prominent for periods longer than two days while there are no favorable intrinsic atmospheric circulation patterns to induce one day of High_PM_2.5, which indicates that a single day of High_PM_2.5 tends to occur by a stochastic atmospheric circulation rather than the intrinsic atmospheric circulation patterns.